Judd-Ofelt Analysis of Nd(TTA)3Phen-doped 6-FDA/Epoxy Planar Waveguides

نویسندگان

  • J. Yang
  • A. Driessen
چکیده

The fluorescent complex Nd(TTA)3Phen (TTA = thenoyltrifluoroacetone, Phen = 1, 10-phenanthroline), was doped into the host material 6-FDA epoxy (6-fluorinated-dianhydride cured epoxy). The room-temperature absorption spectrum of Nd transitions was experimentally obtained, with which the Judd-Ofelt model was applied to determine the Judd-Ofelt parameters. These parameters are used to calculate the emission probabilities of transitions and branching ratios of the Nd from the excited-state F3/2 to lower-lying manifolds. The radiative lifetime of F3/2 was obtained from the emission probabilities. The results of the analysis indicate this Nd (III) complex doped polymer material is promising to be used in planar waveguide lasers and amplifers.

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تاریخ انتشار 2007